The size of the sulphate ion is larger compared to the Group 2 cations. b) Calcium is more reactive. The increasing thermal stability of Group 2 metal salts is consistently seen. Jan 07,2021 - How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? All the Group 2 carbonates and their resulting oxides exist as white solids. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. community of NEET. Mg(s) + H2O(g) → MgO(s) + H2(g) b) Calcium is more reactive. Reactivity of Group II elements increases down the group. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. The thermal stability of Group II carbonates increases as we descend the group. Arrange the following sulphates of alkaline earth metals in order of decreasing thermal stability: . This is clearly seen if we observe the reactions of magnesium and calcium in water. So what causes this trend? The reason, once more, is that the polarising power of the M2+ decreases as ionic radius increases. SOLUBILITY OF THE HYDROXIDES, SULPHATES AND CARBONATES OF THE GROUP 2 ELEMENTS IN WATER This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. As you go down the Group, the carbonates have to be heated more strongly before they will decompose. The Questions and Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. Alkali Earth Metals Group 1. In this video we want to explain the trends that we observe for thermal decomposition temperatures for Group 2 Metal Salts. In this microscale chemistry experiment, from the Royal Society of Chemistry, students investigate the solubility of the group 1 and 2 sulphates and carbonates by reacting small amounts of them on a clear plastic sheet over a worksheet. Solubility: The solubility of the sulphates in water decreases down the groups i.e. In group 1 and 2, the nitrates and carbonates get more stable down the group. (c)Sulphate-thermal stability is good for both alkali and alkaline earth metals. The carbonates become more stable to heat as you go down the Group. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. Less attractions are formed with water molecules. The resource is set out as teachers' notes followed by the students' page which presents the task to be investigated. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. agree to the. 1. solubility: sulphates of alkali metals are soluble in water. are solved by group of students and teacher of NEET, which is also the largest student How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? a) Virtually no reaction occurs between magnesium and cold water. Let's use MgCO 3 as an example. If the answer is not available please wait for a while and a community member will probably answer this BeSO 4 Fairly soluble. Apart from being the largest NEET community, EduRev has the largest solved To help you revise your definitions and equations. It reacts with cold water to produce an alkaline solution of calcium hydroxide and hydrogen gas is released. All these carbonates decompose on heating to give CO 2 and metal oxide. a) Virtually no reaction occurs between magnesium and cold water. 2.0k SHARES. Sulphates: Thermal stability The sulphates of group-1 and group-2 metals are all thermally stable. For Alkaline Earth metals Group 2. Alkali metal sulphates are more soluble in water than alkaline earth metals. Thanks for viewing. All of these carbonates are white solids, and the oxides that are produced are also white solids. However, in a reaction with steam it forms magnesium oxide and hydrogen. over here on EduRev! The solubility also increases down the group for these compounds i-e., Be(OH)2 is less soluble in water as compared to Ba(OH)2. Factors possibly influencing thermal stability of … The solubilities of these salts further increase on descending the group. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Top Be. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. By continuing, I agree that I am at least 13 years old and have read and All the nitrates in this Group undergo thermal decomposition to give the metal oxide, nitrogen dioxide and oxygen. The thermal stability of the nitrates follows the same trend as that of the carbonates, with thermal stability increasing with proton number. Hence polarising ability of the M2+ ion decreases down the group. Bottom Ba. is done on EduRev Study Group by NEET Students. M (OH) 2 + H 2 SO 4 → MSO 4 + 2H 2 O MCO 3 + H 2 SO 4 → MSO 4 + CO 2 + H 2 O . Small highly charged positive ions distort the electron cloud of the anion. Sulphates of alkali metals are soluble in water. However, in a reaction with steam it forms magnesium oxide and hydrogen. All of the Group 2 sulphates consist of 2+ ions attracting 2- ions, and so the only thing that matters is the distance between the ion centres. If you add sodium sulphate or sulphuric acid to an aqueous solution containing calcium, strontium or barium ions a white precipitate forms:. Be > Mg > Ca > Sr > Ba. The thermal decomposition of eleven (II) sulphates has been studied by a combination of thermogravimetric and differential thermal analysis. Charge Density and Polarising Power of Group 2 Metal Cations. Li to Na. Ba 2+ + SO 4 2-(aq) ? Thermal decomposition is the term given to splitting up a compound by heating it. soon. The effect of heat on the Group 2 carbonates. This page looks at the effect of heat on the carbonates and nitrates of the Group 2 elements – beryllium, magnesium, calcium, strontium and barium. Ca(s) + H2O(l) → Ca(OH)2(aq) + H2(g) Ionisation energy decreases due to extra shielding from inner shells and increase in distance from the nucleus. The thermal stability increases down the group for sulphates of alkaline earth metals. The greater the charge density the easier it is for the cation to hydrate and hence dissolve in water due to greater attraction with the polar water molecules. The solubility of carbonates increases down the group in alkali metals (except ) . c i e n o t e s . and big group of compounds are stable with big ionic group. Thermal decomposition of Group 2 nitrates has a similar pattern, decompose to form nitrogen dioxide, oxygen and the oxide: Order of stability: 6 | P a g e h t t p s : / / w w w . 2.0k VIEWS. But carbonates of alkaline earth metals are insoluble in water. EduRev is a knowledge-sharing community that depends on everyone being able to pitch in when they know something. Thermal stability. As you go down the group, the energy needed to break up the lattice falls as the positive ions get bigger. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. Whereas bicarbonates give carbonate, water and carbon dioxide. The relative decomposition temperatures are: MnSO 4 755, FeSO 4 537, CoSO 4 708, NiSO 4 675, CuSO 4 598, ZnSO 4 646, CdSO 4 816, PbSO 4 803, MgSO 4 895, CaSO 4 1149, and SrSO 4 1374°C. It also identifies and explains the trend in the solubility and thermal stability of group 2 metal compounds. The larger compounds further down require more heat than the lighter compounds in order to decompose. This means that beryllium carbonate decomposes at a lower temperature to the rest of the group. However, sulphates of alkaline earth metals show varied trends. It reacts with cold water to produce an alkaline solution of calcium hydroxide and hydrogen gas is released. SrSO 4 (s) (thick white precipitate forms); Ca 2+ + SO 4 2-(aq) ? Question bank for NEET. The solubility of these sulphates decreases as we descend the group, with barium sulphate being insoluble in water. The correct option is: (a) BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Explanation: In all cases, for a particular set of e.g. The thermal decomposition of eleven (II) sulphates has been studied by a combination of thermogravimetric and differential thermal analysis. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. The higher the temperature needed to decompose something, the more thermally stable it is. As the size of the Group 2 cations increases down the group, the difference between the size of the metal cations and the size of the SO 4 2-ions decreases. The term "thermal decomposition" describes splitting up a compound by heating it. Thermal stability of carbonates and nitrates. The solubility of the Group 2 sulphates decreases down the group. The larger the anion the easier the distortion, as seen with the carbonate ion. Properties of Sulphates of Alkali Earth Metals. Learn vocabulary, terms, and more with flashcards, games, and other study tools. | EduRev NEET Question is disucussed on EduRev Study Group … charge density), there is significant difference in terms of their ability to hydrate. Reactivity increases down the group. Alkaline Earth Metals (Group II Elements), Chemical Properties of Alkaline Earth Metals, Transistor Biasing Circuits and Thermal Stability, Group 2 Elements: Alkaline Earth Metals-General Properties. Solubility of Hydroxides and Flourides INCREASES from top to bottom. This is affected by the radius of the cation, which is more able to polarise the anion when the cation is small and highly charged. 000+ LIKES. All group II elements react in air to form an oxide layer. More the strong bonding more thermal stability. Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO 3(s) CaO(s) + CO 2(g) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. All the enthalpy definitions including Lattice Enthalpy, Enthalpy of Hydration and Enthalpy of solutions. The sulphate of alkaline earth metals is less soluble. Arrange sulphates of group in decreasing order of solubility of water. Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO3(s ) CaO(s) + CO2(g ) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. The thermal stability of alkaline earth metals increases down the group for hydroxides i-e., Be(OH)2 is less stable than Ba(OH)2. Magnesium sulphate dissolves in water whereas barium sulphate does not. The greater the distortion caused by the polarising ion the less stable the compound is to heat. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. This is clearly seen if we observe the reactions of magnesium and calcium in water. Thermal Stability is the decomposition of a compound on heating. But group-2 carbonates are soluble in a solution of CO 2 due to formation of HCO 3-. MgCO3(s ) MgO(s) + CO2(g ) Thermal decomposition is defined as the use of heat to break down a reactant into more than one product Thermal stability is the decomposition of compounds on heating. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. MgCO 3(s) MgO(s) + CO 2(g) Thermal decomposition is defined as the use of heat to break down a reactant into more than This trend is explained in terms of the Group II metal ions ability to polarise the anion, the carbonate ion. Group 1 or Group 2 compounds, the thermal stability increases down the group as the ionic radius of the cation increases, and its polarising power decreases. Thermal stability of sulphates of alkaline earth metals increases down the group Ask for details ; Follow Report by Priya4334 22.01.2019 hmmm D.A.V A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. This discussion on How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? As we move down the group 2 the size of cations increases and sulphate is a big ion group according to its size. Solubility of Carbonates and Sulphates DECREASES from top to bottom. However, due to the change in ionic radius (i.e. You can study other questions, MCQs, videos and tests for NEET on EduRev and even discuss your questions like MgSO 4 Soluble. The sulphates of alkaline earth metals are all white solids. Start studying Solubility of Group 2 Hydroxides and Sulphates. Beryllium carbonate decomposing most easily. The relative decomposition temperatures are: MnSO4 755, FeSO4 537, CoSO4 708, NiSO4 675, CuSO4 598, ZnSO4 646, CdSO4 816, PbSO4 803, MgSO4 895, CaSO4 1149, and SrSO4 1374°C. It however shows reversible decomposition in closed container Again the reactivity increases down the group, all forming a white oxide. BaSO 4 (s) (thick white precipitate forms); Sr 2+ + SO 4 2-(aq) ? 3.2k VIEWS. The loss of electrons becomes easier due to the decreasing ionisation energy required. This can be explained by the increase in ease at losing two outer electrons as we descend the group. Reactivity increases down the group. 100+ LIKES. Even for hydroxides we have the same observations. Solubility. Due to the large size of the sulphate anion there is little difference between the lattice energies for these compounds. Solubility of Carbonates INCREASES(opposite of group 2) from top to bottom. FAQs on Appendix - … 3.2k SHARES. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. The effect of heat on the Group 2 nitrates. Group II elements are less reactive than the corresponding Group I element in the same period, since two rather than one electron need to be lost in order to gain noble gas configuration. Thermal stability is a chemical process whereby the components of the lattice react causing decomposion to more stable products. Sulphates of both group 1 and group 2 metals are stable towards heat. 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